{"id":1224,"date":"2021-09-17T10:08:22","date_gmt":"2021-09-17T13:08:22","guid":{"rendered":"https:\/\/nuevocindeca.quimica.unlp.edu.ar\/?page_id=1224"},"modified":"2025-10-22T15:03:42","modified_gmt":"2025-10-22T18:03:42","slug":"desarrollo-de-materiales-hibridos-a-base-de-aluminosilicatos-naturales-y-quimicamente-modificados-aplicacion-en-catalisis-sustentable-procesos-decontaminantes-biomedicina-y-tecnologias-funcionales","status":"publish","type":"page","link":"https:\/\/cindeca.quimica.unlp.edu.ar\/index.php\/desarrollo-de-materiales-hibridos-a-base-de-aluminosilicatos-naturales-y-quimicamente-modificados-aplicacion-en-catalisis-sustentable-procesos-decontaminantes-biomedicina-y-tecnologias-funcionales\/","title":{"rendered":"Desarrollo de materiales h\u00edbridos a base de aluminosilicatos naturales y qu\u00edmicamente modificados. Aplicaci\u00f3n en cat\u00e1lisis sustentable, procesos decontaminantes, biomedicina y tecnolog\u00edas funcionales a la preservaci\u00f3n del medio ambiente."},"content":{"rendered":"\t\t
\n\t\t\t\t\t\t
\n\t\t\t\t\t\t
\n\t\t\t\t\t
\n\t\t\t
\n\t\t\t\t\t\t
\n\t\t\t\t
\n\t\t\t

Investigadora responsable<\/h2>\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t
\n\t\t\t\t\t\t
\n\t\t\t\t\t
\n\t\t\t
\n\t\t\t\t\t\t
\n\t\t\t\t
\n\t\t\t\t\t
\n\t\t\t\n\t\t\t\t\t\t\n\t\t\t\t\t\t\t\t\tProf. Dra. Mercedes Mu\u00f1oz<\/span>\n\t\t\t\t\t<\/span>\n\t\t\t\t\t<\/a>\n\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t
\n\t\t\t\t\t\t
\n\t\t\t\t\t
\n\t\t\t
\n\t\t\t\t\t\t
\n\t\t\t\t
\n\t\t\t

Integrantes<\/h2>\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t
\n\t\t\t\t\t\t
\n\t\t\t\t\t
\n\t\t\t
\n\t\t\t\t\t\t
\n\t\t\t\t
\n\t\t\t\t\t
\n\t\t\t\n\t\t\t\t\t\t\n\t\t\t\t\t\t\t\t\tDra. M. Gabriela Egusquiza<\/span>\n\t\t\t\t\t<\/span>\n\t\t\t\t\t<\/a>\n\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t
\n\t\t\t
\n\t\t\t\t\t\t
\n\t\t\t\t
\n\t\t\t\t\t
\n\t\t\t\n\t\t\t\t\t\t\n\t\t\t\t\t\t\t\t\tDr. Ing. Guillermo Bertolini<\/span>\n\t\t\t\t\t<\/span>\n\t\t\t\t\t<\/a>\n\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t
\n\t\t\t
\n\t\t\t\t\t\t
\n\t\t\t\t
\n\t\t\t\t\t
\n\t\t\t\n\t\t\t\t\t\t\n\t\t\t\t\t\t\t\t\tLic. Pablo Fetsis<\/span>\n\t\t\t\t\t<\/span>\n\t\t\t\t\t<\/a>\n\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t
\n\t\t\t\t\t\t
\n\t\t\t\t\t
\n\t\t\t
\n\t\t\t\t\t\t
\n\t\t\t\t
\n\t\t\t\t\t\t\t

Dise\u00f1o, preparaci\u00f3n y caracterizaci\u00f3n de materiales de alto valor agregado, utilizando como materia prima al\u00famino-silicatos naturales (arcillas, zeolitas, tierras de diatomeas, cenizas volc\u00e1nicas, etc.) procedentes de dep\u00f3sitos minerales no- metal\u00edferos argentinos, de amplia disponibilidad y bajo costo de extracci\u00f3n. El grupo desarrolla t\u00e9cnicas avanzadas de s\u00edntesis y caracterizaci\u00f3n (estructural, espectrosc\u00f3pica, t\u00e9rmica), para obtener sistemas del orden de los nanomateriales, s\u00edntesis e incorporaci\u00f3n de polioxocompuestos (POMs y HPOMs) en matrices ox\u00eddicas, sint\u00e9ticas o naturales. Estos nanomateriales son precursores catal\u00edticos bifuncionales (\u00e1cidos\/redox) en reacciones de bajo impacto ambiental, intercambiadores i\u00f3nicos y adsorbentes para contaminantes. Adem\u00e1s, presentan potencial aplicaci\u00f3n en biomedicina como agentes antitumorales.\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0<\/span><\/p>\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t

\n\t\t\t\t\t\t
\n\t\t\t\t\t
\n\t\t\t
\n\t\t\t\t\t\t
\n\t\t\t\t
\n\t\t\t\t\t\t\t

Publicaciones<\/b><\/span><\/h2>

\u201cPrecursors of tetragonal tungsten bronzes as catalysts in selective reactions: Liquid phase oxidation of diphenyl sulfide and gas phase oxidation of hydrogen sulfide\u201d Egusquiza, M.G., Soriano, M.D., Mu\u00f1oz, M., Romanelli, G., Soriano, J., Cabello, C.I., L\u00f3pez Nieto, J.M (2021) Catalysis Today, 372, pp. 70-81. <\/span><\/p>

“Hydro-adsorption and Textural Properties Study of Microporous Zeolites by Dynamic Laser Speckle Technique\u201d, Mojica-Sepulveda, R. D., Mendoza-Herrera, L. J., Grumel E., Soria D., Cabello C. I., Trivi M., Tebaldi M., \u201cCurrent Perspectives on Chemical Sciences\u201d (2021) Vol. 8, Chapter 5 Print ISBN: 978-93-90768-24-0, eBook ISBN: 978-93-90768-25-7, https:\/\/doi: 10.9734\/bpi\/cpcs\/v8\/7056D. Ed. Book Pub. Int., London UK.<\/span><\/p>

\u201cCatalytic behavior of the WOx-ZrO2<\/sub> system in the clean selective oxidation of diphenyl sulfide (DPS)\u201d Mu\u00f1oz, M., Mendoza-Herrera, L.J., Romanelli, G.P., Gazzoli, D., Cabello, C.I. (2021) Catalysis Today, 372, pp. 146-153.\u00a0<\/span><\/p>

\u201cFabrication of green diatomite\/chitosan-based hybrid foams with dye sorption capacity\u201d Galzerano, B., Cabello, C.I., Mu\u00f1oz, M., Buonocore, G.G., Aprea, P., Liguori, B., Verdolotti, L. (2020) Materials, 13 (17), N\u00b03760.<\/span><\/p>

\u201cCatalytic hydrogenation of nitrate in water. Improvement of the activity and selectivity to N2<\/sub> by using Rh(III)-hexamolybdate supported on ZrO2<\/sub>\u00a0– Al2<\/sub>O3<\/sub>.\u00a0 Jaworski, M.A., Navas, M., Bertolini, G.R., Peroni, M.B., Cabello, C.I., Gazzoli, D., Casella, M.L. (2020) Environmental Technology (United Kingdom), pp. 1-37.\u00a0<\/span><\/span><\/p>

\u201cVolcanic ash as reusable catalyst in the green synthesis of 3H-1,5-benzodiazepines\u201d Mu\u00f1oz, M., Pasquale, G., Sathicq, A.G., Romanelli, G.P., Cabello, C.I., Gazzoli, D. (2019) Green Processing and Synthesis, 8 (1), pp. 600-610.\u00a0<\/span><\/p>

\u201cDynamic laser speckle technique as an alternative tool to determine hygroscopic capacity and specific surface area of microporous zeolites\u201d Mojica-Sepulveda, R. D., Mendoza-Herrera, L. J., Grumel E., Soria D., Cabello C. I., Trivi M., Applied Surface Science 447 (2018) 587-593.<\/span><\/p>

\u201cNovel (NH4<\/sub>)4<\/sub>[NiMo6<\/sub>O24<\/sub>H6<\/sub>]\u00b75H2<\/sub>O \u2013 TiO2<\/sub> composite system: Photo-oxidation of toluene under UV and sunlight-type illumination\u201d Mu\u00f1oz-Batista, M.J., Bertolini, G.R., Cabello, C.I., Luque, R., Rodr\u00edguez-Castell\u00f3n, E., Kubacka, A., Fern\u00e1ndez-Garc\u00eda, M. (2018) Applied Catalysis B: Environmental, 238, pp. 381-392.\u00a0<\/span><\/span><\/p>

\u201cUse of Rh (III)-Heteropolymolybdate as Potential Catalysts for the Removal of Nitrates in Human Drinking Water: Synthesis, Characterisation and Catalytic Performance\u201d Jaworski, M.A., Bertolini, G.R., Cabello, C.I., Siri, G.J., Casella, M.L. (2018) Water, Air, and Soil Pollution, 229 (9), art. no. 309.\u00a0<\/span><\/p>

\u201cMolybdenum-containing systems based on natural kaolinite as catalysts for selective oxidation of aromatic sulfides\u201d Mu\u00f1oz, M., Gallo, M.A., Guti\u00e9rrez-Alejandre, A., Gazzoli, D., Cabello, C.I (2017) Applied Catalysis B: Environmental, 219, pp. 683-692.\u00a0<\/span><\/p>

\u201cComposites based on modified clay assembled Rh(III)\u2013heteropolymolybdates as catalysts in the liquid-phase hydrogenation of cinnamaldehyde\u201d Bertolini, G.R., Vetere, V., Gallo, M.A., Mu\u00f1oz, M., Casella, M.L., Gambaro, L., Cabello, C.I. (2016) Comptes Rendus Chimie, 19 (10), pp. 1174-1183.\u00a0<\/span><\/p>

\u201cPolyoxometalates as antitumor agents: Bioactivity of a new polyoxometalate with copper on a human osteosarcoma model\u201d Le\u00f3n, I.E., Porro, V., Astrada, S., Egusquiza, M.G., Cabello, C.I., Bollati-Fogolin, M., Etcheverry, S.B. (2014) Chemico-biological interactions, 222, pp. 87-96.\u00a0<\/span><\/p>

\u201cPorous modified bentonite as efficient and selective catalyst in the synthesis of 1,5-benzodiazepines\u201d Mu\u00f1oz, M., Sathicq, G., Romanelli, G., Hern\u00e1ndez, S., Cabello, C.I., Botto, I.L., Capron, M. (2013) Journal of Porous Materials, 20 (1), pp. 65-73.\u00a0<\/span><\/p>

\u201cCatalysts based on Rh(III)-hexamolybdate\/\u03b3-Al2<\/sub>O3<\/sub> and their application in the selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde\u201d Bertolini, G.R., Cabello, C.I., Mu\u00f1oz, M., Casella, M., Gazzoli, D., Pettiti, I., Ferraris, G. (2013) Journal of Molecular Catalysis A: Chemical, 366, pp. 109-115.\u00a0<\/span><\/span><\/p>

\u201cSynthesis and spectroscopic 27<\/sup>Al NMR and Raman characterization of new materials based on the assembly of [AlO4<\/sub>Al12<\/sub>(OH)24<\/sub>(H2<\/sub>O)12<\/sub>]<\/span>7+ <\/sup><\/span>isopolycation and Co-Cr and [AlMo6<\/sub>O24<\/sub>H6<\/sub>]3-<\/sup> Anderson heteropolyanions\u201d Mu\u00f1oz, M., Cabello, C.I., Botto, I.L., Minelli, G., Capron, M., Lamonier, C., Payen, E. (2007) Journal of Molecular Structure, 841 (1-3), pp. 96-103.\u00a0<\/span><\/span><\/p>

\u201cThe role of Rh on a substituted Alnderson heteropolymolybdate: Thermal and hydrotreating catalytic behavior\u201d Cabello, C.I., Mu\u00f1oz, M., Botto, I.L., Payen, E. (2006) Thermochimica Acta, 447 (1), pp. 22-29.\u00a0<\/span><\/p>

\u201cApplication of complex heteropolytungstates in limonene epoxidation by H2<\/sub>O2<\/sub> in biphasic medium\u201d Casuscelli, S., Herrero, E., Crivello, M., P\u00e9rez, C., Egusquiza, M.G., Cabello, C.I., Botto, I.L. (2005) Catalysis Today, 107-108, pp. 230-234.\u00a0<\/span><\/span><\/p>

\u201cHeteropolyoxotungstates containing a wide catalytic target: Reducibility and thermal stability\u201d Cabello, C.I., Egusquiza, M.G., Botto, I.L., Minelli, G (2004) Materials Chemistry and Physics, 87 (2-3), pp. 264-274.<\/span><\/p>

\u201cDecamolybdodicobaltate(III) heteropolyanion: Structural, spectroscopical, thermal and hydrotreating catalytic properties\u201d Cabello, C.I., Cabrerizo, F.M., Alvarez, A., Thomas, H.J. (2002) Journal of Molecular Catalysis A: Chemical, 186 (1-2), pp. 89-100.\u00a0<\/span><\/p>

\u201cAnderson-type heteropolyoxomolybdates in catalysis: 2. EXAFS study on \u03b3-Al2<\/sub>O3<\/sub>-supported Mo, Co and Ni sulfided phases as HDS catalysts\u201d Pettiti, I., Botto, I.L, Cabello, C.I, Colonna, S., Faticanti, M., Minelli, G., Porta, P., Thomas, H.J. (2001) Applied Catalysis A: General, 220 (1-2), pp. 113-121.<\/span><\/p>

\u201cAnderson type heteropolyoxomolybdates in catalysis: 1. (NH4<\/sub>)3<\/sub>[CoMo6<\/sub>O24<\/sub>H6<\/sub>]\u00b77H2<\/sub>O\/\u03b3-Al2<\/sub>O3<\/sub> as alternative of Co-Mo\/\u03b3-Al2<\/sub>O3<\/sub> hydrotreating catalysts\u201d Cabello, C.I., Botto, I.L., Thomas, H.J. (2000) Applied Catalysis A: General, 197 (1), pp. 79-86.\u00a0<\/span><\/span><\/p>\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<\/div>\n\t\t","protected":false},"excerpt":{"rendered":"

Investigadora responsable Prof. Dra. Mercedes Mu\u00f1oz Integrantes Dra. M. Gabriela Egusquiza Dr. Ing. Guillermo Bertolini Lic. Pablo Fetsis Dise\u00f1o, preparaci\u00f3n y caracterizaci\u00f3n de materiales de alto valor agregado, utilizando como materia prima al\u00famino-silicatos naturales (arcillas, zeolitas, tierras de diatomeas, cenizas volc\u00e1nicas, etc.) procedentes de dep\u00f3sitos minerales no- metal\u00edferos argentinos, de amplia disponibilidad y bajo costo … <\/p>\n

Segu\u00ed leyendo “Desarrollo de materiales h\u00edbridos a base de aluminosilicatos naturales y qu\u00edmicamente modificados. Aplicaci\u00f3n en cat\u00e1lisis sustentable, procesos decontaminantes, biomedicina y tecnolog\u00edas funcionales a la preservaci\u00f3n del medio ambiente.”<\/span><\/a><\/p>\n","protected":false},"author":8,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"_links":{"self":[{"href":"https:\/\/cindeca.quimica.unlp.edu.ar\/index.php\/wp-json\/wp\/v2\/pages\/1224"}],"collection":[{"href":"https:\/\/cindeca.quimica.unlp.edu.ar\/index.php\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/cindeca.quimica.unlp.edu.ar\/index.php\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/cindeca.quimica.unlp.edu.ar\/index.php\/wp-json\/wp\/v2\/users\/8"}],"replies":[{"embeddable":true,"href":"https:\/\/cindeca.quimica.unlp.edu.ar\/index.php\/wp-json\/wp\/v2\/comments?post=1224"}],"version-history":[{"count":128,"href":"https:\/\/cindeca.quimica.unlp.edu.ar\/index.php\/wp-json\/wp\/v2\/pages\/1224\/revisions"}],"predecessor-version":[{"id":8387,"href":"https:\/\/cindeca.quimica.unlp.edu.ar\/index.php\/wp-json\/wp\/v2\/pages\/1224\/revisions\/8387"}],"wp:attachment":[{"href":"https:\/\/cindeca.quimica.unlp.edu.ar\/index.php\/wp-json\/wp\/v2\/media?parent=1224"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}